Marine Chemistry in the Coastal Environment: Principles,Perspective and Prospectus   总被引：1，自引：1，他引：0  

Thomas M. Church 《Aquatic Geochemistry》2016,22(4):375-389

Marine chemistry of the coastal environment starts with principles of rock weathering that use carbonic acid to mobilize elements, only some of which comprise the majority of sea salt. The principle reason is reverse weathering, extensively represented in coastal waters, and returns most elements to newly formed colloids or minerals while recycling carbon dioxide to the atmosphere. This includes the deeper ocean expanse of sediment diagenesis, plus hydrothermal plumes and attendant low-temperature basalt alteration. Within the estuarine and extended shelf regimes, both conservative and non-conservative processes can be distinguished and modeled to determine proportions of weathered elements transmitted to the sea or consumed by reverse weathering. Conceptually, the steady-state processes that lead to the composition of seawater can be viewed as heterogeneous equilibria between dissolved constituents and solid mineral products taking hundreds of millennia. However, initial processes in the estuarine and coastal environment are characterized by shorter term scavenging associated with inorganic and organic colloids. These recycle both carbon and trace elements on timescales commensurate with estuarine flushing and coastal exchange with the ocean. The natural uranium and thorium decay series provide powerful tools for quantifying the rates of estuarine processes, including those within groundwater and the subterranean estuary. In the future, new mass spectrometric and nuclear magnetic resonance techniques will help to define the molecular nature of newly formed estuarine colloids as has been done for dissolved organic matter. As the coastal environment undergoes the forces of climate change in the form of warming and sea level rise, future research should address how these will impact chemistry of the coastal environment as a net source or sink of carbon dioxide and associated organic material.  相似文献   

Hierarchical simulation of aquifer heterogeneity: implications of different simulation settings on solute-transport modeling     

Alessandro Comunian  Leonardo De Micheli  Claudio Lazzati  Fabrizio Felletti  Francesca Giacobbo  Mauro Giudici  Riccardo Bersezio 《Hydrogeology Journal》2016,24(2):319-334

The fine-scale heterogeneity of porous media affects the large-scale transport of solutes and contaminants in groundwater and it can be reproduced by means of several geostatistical simulation tools. However, including the available geological information in these tools is often cumbersome. A hierarchical simulation procedure based on a binary tree is proposed and tested on two real-world blocks of alluvial sediments, of a few cubic meters volume, that represent small-scale aquifer analogs. The procedure is implemented using the sequential indicator simulation, but it is so general that it can be adapted to various geostatistical simulation tools, improving their capability to incorporate geological information, i.e., the sedimentological and architectural characterization of heterogeneity. When compared with a standard sequential indicator approach on bi-dimensional simulations, in terms of proportions and connectivity indicators, the proposed procedure yields reliable results, closer to the reference observations. Different ensembles of three-dimensional simulations based on different hierarchical sequences are used to perform numerical experiments of conservative solute transport and to obtain ensembles of equivalent pore velocity and dispersion coefficient at the scale length of the blocks (meter). Their statistics are used to estimate the impact of the variability of the transport properties of the simulated blocks on contaminant transport modeled on bigger domains (hectometer). This is investigated with a one-dimensional transport modeling based on the Kolmogorov-Dmitriev theory of branching stochastic processes. Applying the proposed approach with diverse binary trees and different simulation settings provides a great flexibility, which is revealed by the differences in the breakthrough curves.  相似文献   

The hydrogeology of the military inundation at the 1914–1918 Yser front (Belgium)     

Alexander Vandenbohede 《Hydrogeology Journal》2016,24(2):521-534

Protection against flooding by the sea, drainage of rainwater and integrated management of groundwater and surface-water resources are key issues in low-lying coastal areas. However, under exceptional circumstances, knowledge to keep coastal areas dry and habitable can be used otherwise. Inundation for military purposes is such an example. The hydrogeology of the inundation at the Yser River, Belgium, during the Great War is studied. The inundation started in October 1914 to stop the German advance and lasted until 1918. A water balance and groundwater model are combined to derive the water balance before and during the inundation and to study the impact on the groundwater system. It is concluded that a number of hydrogeological factors contributed to the effectiveness of the inundation. Most importantly, the low-permeability subsoil facilitated loss of inundation water mainly by evaporation. Further, the normal water management strategy of the area (aimed at evacuating excess water towards the sea) was reversed to keep water between the opposing armies. However, the duration of the inundation meant a reorganization of the drainage of areas not inundated; truly an exercise in integrated water management.  相似文献   

Impacts of a large Sahelian city on groundwater hydrodynamics and quality: example of Niamey (Niger)     

Aïssata B. Hassane  Christian Leduc  Guillaume Favreau  Barbara A. Bekins  Thomas Margueron 《Hydrogeology Journal》2016,24(2):407-423

The management of groundwater resources is very important in the semiarid Sahel region, which is experiencing rapid urban development. Impacts of urbanization on groundwater resources were investigated in the unconfined aquifer of the Continental Terminal beneath the city of Niamey, Niger, using water level and chemical data. Hydrodynamic and chemical changes are best described by a combination of factors including the historical development of the city, current land use, water-table depth and topography. Seasonal groundwater recharge occurs with high spatial variability, as indicated by water-level monitoring in all wells, but there was no interannual trend over the 5-year study period. Groundwater salinity shows high spatial variability and a minor rising trend. The highest salinity is in the old city centre, with Na–NO₃ dominant, and it increases seasonally with recharge. Salinity is much lower and more variable in the suburbs (Ca–HCO₃, Ca–NO₃, and Na–NO₃ dominant). Nitrate is the main ionic contaminant and is seasonally or permanently above the international guidelines for drinking water quality in 36 % of sampled wells, with a peak value of 112 mg L^?1 NO₃–N (8 meq L^?1). Comparison of urban and rural sites indicates a long-term increase in groundwater recharge and nitrate enrichment in the urban area with serious implications for groundwater management in the region.  相似文献   

Steady critical discharge rates from vertical and horizontal wells in fresh–saline aquifers with sharp interfaces     

Raziyeh Hendizadeh  Mazda Kompanizare  Mohammad R. Hashemi  G. Reza Rakhshandehroo 《Hydrogeology Journal》2016,24(4):865-876

In this study, the critical (or maximum) discharge rates before saline water enters a well were determined for vertical and horizontal wells in a freshwater aquifer which is separated from a static saline aquifer by a sharp interface. Flow around the well was solved by integration of a point sink solution along the well axis, and both the critical discharge rate and critical interface rise were determined through a comparison of the heads and vertical gradients at the saline–fresh water interface. The rates were determined for vertical and horizontal wells with various lengths and depths for different aquifer salinities. Results were generalized by drawing dimensionless type curves. The results showed that the dimensionless total critical discharge rates are higher for the longer horizontal wells and longer vertical wells with a certain bottom depth, and they almost linearly decrease with well depth at rates of 0.7–0.9. For the dimensionless well length of 0.2, the dimensionless total discharge rate of a horizontal well is about 0.1 more than that of a vertical well with the same length and well-top depth. Also, the critical discharge rates per unit length of well are inversely proportional to well length and remarkably higher for shallower wells. Additionally, the critical pumping rate is proportional to the salinity difference of the aquifers. These results were confirmed by comparison to existing solutions for vertical wells with dimensionless lengths of 0.2, 0.5 and 0.6, and for critical interface rises in the range of 0.75–0.9.  相似文献   

Measures for groundwater security during and after the Hanshin-Awaji earthquake (1995) and the Great East Japan earthquake (2011), Japan     

Tadashi Tanaka 《Hydrogeology Journal》2016,24(2):277-286

Many big earthquakes have occurred in the tectonic regions of the world, especially in Japan. Earthquakes often cause damage to crucial life services such as water, gas and electricity supply systems and even the sewage system in urban and rural areas. The most severe problem for people affected by earthquakes is access to water for their drinking/cooking and toilet flushing. Securing safe water for daily life in an earthquake emergency requires the establishment of countermeasures, especially in a mega city like Tokyo. This paper described some examples of groundwater use in earthquake emergencies, with reference to reports, books and newspapers published in Japan. The consensus is that groundwater, as a source of water, plays a major role in earthquake emergencies, especially where the accessibility of wells coincides with the emergency need. It is also important to introduce a registration system for citizen-owned and company wells that can form the basis of a cooperative during a disaster; such a registration system was implemented by many Japanese local governments after the Hanshin-Awaji Earthquake in 1995 and the Great East Japan Earthquake in 2011, and is one of the most effective countermeasures for groundwater use in an earthquake emergency. Emphasis is also placed the importance of establishing of a continuous monitoring system of groundwater conditions for both quantity and quality during non-emergency periods.  相似文献   

Effects of nonlinear model response on allocation of streamflow depletion: exemplified by the case of Beaver Creek,USA     

David P. Ahlfeld  James C. Schneider  Charles P. Spalding 《Hydrogeology Journal》2016,24(7):1835-1845

Anomalies found when apportioning responsibility for streamflow depletion are examined. The anomalies arise when responsibility is assigned to the two states that contribute to depletion of Beaver Creek in the Republican River Basin in the United States. The apportioning procedure for this basin presumes that the sum of streamflow depletions, computed by comparing simulation model runs with and without groundwater pumping from individual states, approximates the streamflow depletion when both states are pumping. In the case study presented here, this presumed superposition fails dramatically. The stream drying and aquifer-storage depletion, as represented in the simulation model used for allocation, are examined in detail to understand the hydrologic and numerical basis for the severe nonlinear response. Users of apportioning procedures that rely on superposition should be aware of the presence and likely magnitude of nonlinear responses in modeling tools.  相似文献   

The Great Artesian Basin: is it that great?     

Elad Dafny 《Hydrogeology Journal》2016,24(6):1329-1332

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Assessment of small-diameter shallow wells for managed aquifer recharge at a site in southern Styria,Austria     

Falk Händel  Gaisheng Liu  Johann Fank  Franz Friedl  Rudolf Liedl  Peter Dietrich 《Hydrogeology Journal》2016,24(8):2079-2091

An approach to establish the recharge component of managed aquifer recharge (MAR) has recently been proposed that uses small-diameter shallow wells installed using relatively inexpensive drilling methods such as direct push. As part of further development of that approach, a generalized procedure is presented for a technical and economic assessment of the approach’s potential in comparison to other systems. Following this procedure, the use of small-diameter wells was evaluated both experimentally and numerically for a site located in southern Styria, Austria. MAR is currently done at the site using a horizontal pipe infiltration system, and system expansion has been proposed with a target rate of 12 l/s using small-diameter wells as one possible option. A short-duration single-well field recharge experiment (recharge rate 1.3–3.5 l/s) was performed (recharge by gravity only). Numerical modeling of the injection test was used to estimate hydraulic conductivity (K). Quasi-steady-state, single-well recharge simulations for different locations, as well as a long-term transient simulation, were performed using the K value calibrated from the field injection test. Results indicate that a recharge capacity of 4.1 l/s was achievable with a maximum head rise of 0.2 m at the injection well. Finally, simulations were performed for three different well fields (4, 6 and 8 wells, respectively) designed to infiltrate a target rate of 12 l/s. The experimental and numerical assessments, supported by a cost analysis of the small-diameter wells, indicate that the small-diameter wells are a viable, cost-effective recharge approach at this and other similar sites.  相似文献   

A multi-tracer approach to delineate groundwater dynamics in the Rio Actopan Basin,Veracruz State,Mexico     

Juan Pérez Quezadas  Victor M. Heilweil  Alejandra Cortés Silva  Luis Araguas  María del Rocío Salas Ortega 《Hydrogeology Journal》2016,24(8):1953-1966

Geochemistry and environmental tracers were used to understand groundwater resources, recharge processes, and potential sources of contamination in the Rio Actopan Basin, Veracruz State, Mexico. Total dissolved solids are lower in wells and springs located in the basin uplands compared with those closer to the coast, likely associated with rock/water interaction. Geochemical results also indicate some saltwater intrusion near the coast and increased nitrate near urban centers. Stable isotopes show that precipitation is the source of recharge to the groundwater system. Interestingly, some high-elevation springs are more isotopically enriched than average annual precipitation at higher elevations, indicating preferential recharge during the drier but cooler winter months when evapotranspiration is reduced. In contrast, groundwater below 1,200 m elevation is more isotopically depleted than average precipitation, indicating recharge occurring at much higher elevation than the sampling site. Relatively cool recharge temperatures, derived from noble gas measurements at four sites (11–20 °C), also suggest higher elevation recharge. Environmental tracers indicate that groundwater residence time in the basin ranges from 12,000 years to modern. While this large range shows varying groundwater flowpaths and travel times, ages using different tracer methods (¹⁴C, ³H/³He, CFCs) were generally consistent. Comparing multiple tracers such as CFC-12 with CFC-113 indicates piston-flow to some discharge points, yet binary mixing of young and older groundwater at other points. In summary, groundwater within the Rio Actopan Basin watershed is relatively young (Holocene) and the majority of recharge occurs in the basin uplands and moves towards the coast.  相似文献